Agotime Ziope formerly Adaklu Anyibe is one of the twenty five (25) Municipalities and Districts in the Volta Region of Ghana. The Administrative Capital of the District is Kpetoe. Agotime-Ziope District is bordered by the Republic of Togo to the East; Akatsi North and Central Tongu Districts to the South and the Adaklu District to the West and North. The District covers a total land area of about Six Hundred and Thirty-Seven kilometres square (637km2).

The population of the municipality according to 2010 population and housing census stands at 34,456 with 16,788 males and 17,668 females.